Nafion-carbon nanocomposite membranes prepared using hydrothermal carbonization for proton-exchange-membrane fuel cells


Nafion-carbon (NC) composite membranes were prepared by hydrothermal treatment of Nafion membrane impregnated with glucose solution. The carbon loading of the NC membrane was tuned by controlling the hydrothermal carbonization time. X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, and positron annihilation lifetime spectroscopy were used to characterize plain Nafion and NC composite membranes. Nafion-carbon composite membranes exhibited better proton conductivity and reduced methanol permeability than those of the plain Nafion membrane. A single cell prepared with the NC composite membrane with a carbon loading of 3.6 wt% exhibited the highest cell performance. Compared with the cell performance of plain Nafion membrane, the maximum power density of the new cell improved by 31.7% for an H2/O2 fuel cell at room temperature, and by 44.0% for a direct methanol fuel cell at 60 °C. Nafion-carbon nanocomposite membranes (see graphic) are synthesized by infiltrating Nafion 117 membranes with glucose solution, followed by hydrothermal treatment. The carbon content is controlled by the hydrothermal treatment duration. Nanocomposite membranes with high carbon loading have low methanol permeability and high proton conductivity, and produce maximum power densities in H2/O2 and direct methanol fuel cells of 31.7% and 44.0% higher than those of Nafion 117 membranes, respectively. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Advanced Functional Materials